Phase transitions in tris-sarcosine calcium chloride (TSCC) to 14 GPa
نویسندگان
چکیده
منابع مشابه
Phase transitions in biogenic amorphous calcium carbonate.
Crystalline biominerals do not resemble faceted crystals. Current explanations for this property involve formation via amorphous phases. Using X-ray absorption near-edge structure (XANES) spectroscopy and photoelectron emission microscopy (PEEM), here we examine forming spicules in embryos of Strongylocentrotus purpuratus sea urchins, and observe a sequence of three mineral phases: hydrated amo...
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W. Bi,1 Y. Meng,2 R. S. Kumar,3 A. L. Cornelius,3 W. W. Tipton,4 R. G. Hennig,4 Y. Zhang,3 C. Chen,3 and J. S. Schilling1 1Department of Physics, Washington University, CB 1105, One Brookings Dr., St. Louis, Missouri 63130, USA 2HPCAT, Carnegie Institution of Washington, 9700 S. Cass Ave., Argonne, Illinois 60439, USA 3Department of Physics and High Pressure Science and Engineering Center, Univ...
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We have studied the phase transitions in atomic clusters by molecular dynamics simulation, assuming Lennard-Jones interatomic pair potential. Calculations are performed by DAP parallel computer. The results are analyzed by simulating their orientational distribution plots (dot-plot), and neutron diffraction patterns. It is shown that all the main features of the bulk phase transitions are e...
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In the title compound, (C(7)H(10)N)(3)[SbCl(5)]Cl, the Sb(III) cation is coordinated by five Cl(-) anions in a distorted square-pyramidal geometry, in which the longest Sb-Cl distance of 3.0319 (14) Å indicates a weak coordination bond. In the crystal, the 3-methyl-anilinium cations link with the complex antimonate anions and Cl(-) anions via N-H⋯Cl hydrogen bonds.
متن کاملTris(4-methylanilinium) pentachloridoantimonate(III) chloride monohydrate
The title compound, (C(7)H(10)N)(3)[SbCl(5)]Cl·H(2)O, consists of 4-methyl-anilinium cations, Cl(-) and [SbCl(5)](2-) anions and water mol-ecules. The five Cl atoms bound to Sb [Sb-Cl = 2.4043 (9)-2.6262 (11) Å] form a square-pyramidal coordination environment. In addition, two [SbCl(5)](2-) anions related by an inversion center are joined by Sb⋯Cl inter-actions [Sb⋯Cl = 3.7273 (14) Å] into an ...
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ژورنال
عنوان ژورنال: Ferroelectrics
سال: 1993
ISSN: 0015-0193,1563-5112
DOI: 10.1080/00150199308222452